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Both Photocouplers and Optical-coupled MOSFETs(OCMOS FETs) transmit signals while remaining electrically isolated.
Therefore, there may be some people who worry about difference of them.
Then, we would like to describe their differences below.
The figures below show the principal internal structures of a photocoupler and an OCMOS FET.

As shown in the photocoupler on the left, when the light emitting diode (LED) lights up the phototransistor, the light generates a photocurrent that flows from the collector to the base of the phototransistor.
Accordingly, when the LED does not light up, the phototransistor is cutting off, and when the LED lights strongly, a large photocurrent flows from the collector to the base and the phototransistor is turned on steadily.
Unlike when the base-collector is simply short-circuited, even if the collector-emitter voltage is less than the base-emitter forward voltage of a transistor, the photocurrent still flows and the phototransistor is conductive.
On the other hand, as shown in the figure on the right above, the OCMOS FET incorporates photovoltaic cells, and when the LED lights up, the photovoltaic cells charge the gate capacitance to increase the gate-source voltage, turning on the MOS FETs in the case of a make-type contact.
For a break-type contact, the FETs are conductive with no gate-source voltage. However, when the LED is lit, the photovoltaic cells bias the gate-source voltage reversely, cutting off the FETs.
When the make-type OCMOS FET is turned off, the photovoltaic cells not only stop charging but the internal discharger switch is automatically closed, forcing the gates to discharge. As a result, the gate-source voltage immediately drops.
Two FETs in an OCMOS FET are serially connected in reverse together. Therefore, when the OCMOS FET is conductive, both of the FETs conduct bidirectionally. However, when the OCMOS FET is not conductive, only the FET which is forward direction with the applied voltage cut off, while a parasitic diode of the another FET conducts.
Because of these structural differences above, photocouplers and OCMOS FETs have the characteristic differences as follows:
Therefore, although high-speed operation like a photocoupler cannot be expected for OCMOS FETs, OCMOS FETs can switch AC and also a large current in the ampere range with a small input current (as small as a few milliampere).
In general the photocoupler is used only for the transmission of a DC signal. Its applications include:


On the other hand, because an OCMOS FET's operating speed is slower than that of a photocoupler, it is rarely used for signal transmission.
However, because of the MOSFET's bidirectional conduction and low on-resistance features, it is mainly used as an "electronic switch" that intermits AC signals.
Therefore OCMOS FETs are also called an SSR (Solid State Relay).
